Consejo Superior de Investigaciones Científicas posted this:Enzymatic production of 2,5-furandicarboxylic acid from 5-methoxymethylfurfuraCSIC, University of Zaragoza and Technische Universität Dresden have developed an enzymatic composition and its use as an enzymatic cascade for the production of 2,5-furandicarboxylic acid (FDCA) from 5-methoxymethylfurfural (MMF). This cascade is self-sustained with the only consumption of atmospheric oxygen and the MMF itself. The method can be applied to the conversion of MMF into FDCA step in the bioplastic producing industry, switching from the current inorganic catalysts employed to the use of enzymes for the FDCA production. Industrial partners are being sought to develop and commercialize the enzymatic composition through a patent licence agreement. An offer for Patent Licensing
Research & Technology Organization
Technology Transfer Office
Institut Català d'Investigació Química (ICIQ) posted this:Photoinitiators for visible-light induced living polymerizationA new class of photoinitiators of living polymerization induced by visible light has been developed and is made available for testing (under MTA) and/or licensing. The developed initiators trigger the curing of resins by irradiation with low-intensity visible light, while providing polymers with good control of chain length. In addition, through decomposition of the initator, the cured material presents a different colour than the uncured resin.
Germán Cabañero posted this:
HEAD OF STRATEGIC PARTNERSHIP at CIDETEC
Cracow University of Technology posted this:Photosensitizers for photocurable polymer coatingThe technology can be used in the production of polymer coatings curable by ultraviolet radiation (UV) imposed on various types of surface such as aluminum, paper, plastics, wood and metals. Technology is compatible with UV LED diodes, which make it advantageous in several fields comparing to traditional mercury MPM lamps
uacoopera posted this:Process for converting waste, effluents and organic by-products in recyclable materialsA group of researchers from a Portuguese university has developed a biological process to treat waste, effluents and organic by-products with industrial origin characterized by high biodegradability that adds value to conventional biological treatment processes, integrating their assumptions on the concept of biorefinery. The invention aims to reduce by 96% the organic matter content of the starting substrate allowing generally meet the discharge criteria set out in the legislation.
uacoopera posted this:Ohmic heating reactor for chemical synthesis, the method and its applicationsIn ohmic heating electrical energy is dissipated in heat with a very high efficiency (electrodes in contact with the reaction medium), resulting in fast and uniform heating and in the increase of charged species movement. As in the case of the heating with microwave radiation, electrical energy is transformed into thermal energy. However, on contrary of heating with microwave radiation (penetration depth of microwave radiation in absorbing media is limited) the penetration depth is virtually unlimited and the extent of heating is regulated only by the spatial uniformity of electrical conductivity throughout the reaction medium and the time spent in the ohmic reactor. Thus, the direct scaling of the ohmic heating for the pilot or industrial scale shouldn’t have the limitations presented by microwave radiation heating. It is also possible to reduce reaction times and increase the energy efficiency of chemical reactions
Cracow University of Technology posted this:Novel transparent polymer nanocomposites based on PMMA and inorganic semiconductor nanoparticles for optoelectronics applicationsA method of preparing novel and transparent polymer nanocomposites based on a polymeric matrix of polymethyl methacrylate (PMMA) and the inorganic nanoparticles of zinc sulfide doped with manganese atoms (ZnS:Mn).
University of Vigo posted this:A novel mild and efficient method to prepare ε-Caprolactam precursor of Nylon 6ε-Caprolactam, the main precursor of the synthetic fibber Nylon 6, is prepared from cyclohexanone oxime by treatment with a new salt as promoter. This procedure requires mild reaction conditions and affords excellent levels of conversion and selectivity to obtain pure ε-caprolactam. No reaction by-products are formed. The new promoter salt is cheap, no corrosive, and easy to prepare. All these characteristics makes the procedure suitable for undustrial purposes.
Universidad de Alicante posted this:Method for recycling of vessels and other structures composed of fiberglass and resinResearchers at the University of Alicante have developed a method to recycle composite fiberglass structures on a polymer matrix (resin). The process removes the polymer matrix, recovering glass fiber which can be reused. The process is not aggressive with fiberglass. It takes place at room temperature and is able to recover all the fiberglass used. The method is industrially scalable and can be automated. Fiberglass composites and resin are widely used in the construction of boat hulls, tanks, wind turbine blades and many other applications. This method is a very important innovation for the sector and there was no effective method that allowed recovering and reusing these materials.
Institute of Chemical Research of Catalonia posted this:New method to produce trifluoromethyl copper reagents useful in trifluoromethylation reactions from fluoroformThe trifluoromethyl copper derivative useful in trifluoromethylation reactions is prepared at room temperature from readily available and cheap reagents and in high yield, i.e. without the formation of side-products associated to the fast decomposition of the trifluoromethyl anion, that usually forms in processes involving the deprotonation of fluoroform. This is the first method to date for deprotonation-free, direct cupration of fluoroform, a longly sought after reaction.
Universidad de Alcalá-OTRI posted this:New organo-metallic catalysts for the manufacture of polymersA research group from the Inorganic Chemistry Department of Alcalá University has developed a technology that presents a range of catalysts based on coordination complexes and organometallic, active in functionalization processes (expoditation, hydrosilylation) and polymerization of different organic substrates (olefins and cyclic esters). They are metal complexes belonging to the first transition groups (groups 4-6) and elements from the main groups (groups 1,2 and 13). Its application is aimed at the synthesis of materials with new properties (silicon polymers, biodegradable plastics, polyesters) and the production of small molecules with high added value, used as starting products in many industrial processes (epoxides, silanes). The group is looking for manufacturing agreements and joint venture agreements with companies from the agrofood industry, construction and petrochemicals.
DIT Hothouse posted this:iSeal: Advanced Surface Treatment for Protection against TribocorrosionThis invention is based on the application of a hybrid organic/inorganic treatment onto an exposed surface – either as a stand-alone treatment or as a sealant. The treatment is applied using an electrochemical deposition technique, allowing for the development of conformal coatings, irrespective of design complexity. Layer thicknesses are low (10-100nm) but resistance in corrosive marine environments indicate corrosion rates comparable to technologies currently employed by the aerospace and automotive industries. Corrosion rates are reduced by between 103 and 105 times, dependant on the nature of the porous coating. Tests on metallic coatings indicated a reduction in corrosion rates of approximately 103-104 while tests on ceramic coatings indicated a reduction in corrosion rates of approximately 105. By applying the hybrid treatment as a sealant treatment onto a porous wear resistant coating, concerns regarding the effect of mechanical damage are dramatically reduced. In addition, surface roughness levels are similar to electropolished finishes.