Universitat de València

Environmentally friendly colorimetric sensors for detecting hydrogen cyanide (HCN)

Posted by Universitat de ValènciaResponsive · Patents for licensing · Spain

Summary of the technology

The main advantages provided by the this colorimetric sensor are:
- Detection Limits: The direct reaction between the sensor and the HCN leads to a marked color change with detection limits below 1 ppm.
- Selectivity: in the presence of other gases such as CO, HCl, NH3, H2S, at concentrations up to 50 ppm
- Environmentally friendly: no heavy metals used.
- Reversibility: The reaction is reversible by irradiation with UV light so it can be reused in successive cycles
- Minimizing false positives: Regeneration by UV radiation occurs only if the sensor reacted with HCN.

Description of the tech for sale

Both cyanide anion in solution (CN-) and hydrogen cyanide as a gas (HCN) are contaminant molecules, extremely toxic and dangerous in both physiological systems and in the environment. Currently, there are many colorimetric sensors for detection of CN-, however they generally do not offer adequate selectivity in the presence of other pollutants. Regarding the detection of HCN, colorimetric systems marketed so far use an indirect route for the detection, with a pH indicator which detects the HCl generated by the reaction of HCN with HgCl2. The use of this type of mercury salts generates a significant pollutant load, what makes especially interesting the fact of looking for new effective and environmentally friendly alternatives. Spanish Researchers have designed new colorimetric sensors for CN- and HCN, which have excellent selectivity and detection limits within the commonly accepted security ranges.

Specifications

For both applications, the invention is based on the use of a diphenylmethane-quinone compound. For the specific case of HCN gas, the compound is deposited on a solid support of basic nature. The correct choice of the compound has allowed obtaining a carbon center with electrophilicity suitable for the cyanide anion. This compound, unlike other similar commercial molecules, maintains its characteristics and reactivity once deposited on a suitable solid support. Thus, researchers have designed the first colorimetric sensor for gaseous HCN, with direct reaction. The technology is fully developed and available for demonstration. It could be useful in industries generating HCN as life safety system.

Main advantages of its use

  • The major innovation of this invention is the fact of developing new colorimetric sensors for detecting hydrogen cyanide without using heavy metals.

Applications

  • The invention is applicable to the fabrication of sensing devices, especially as life safety systems. . These systems are useful in various industrial sectors that generate HCN (wood, plastic, steel, jewelry, mining, petrochemical, etc.) as well as in public buildings susceptible to attacks (stations, airports, etc).

Related keywords

  • Industrial Technologies
  • Physical Sciences and Exact Sciences
  • Protecting Man and Environment
  • Biological Sciences
  • Hydrogen production
  • Chemistry
  • Environment
  • Industrial Products
  • Medical Health related
  • Genetic Engineering / Molecular Biology
  • sensors
  • colorimetric sensor
  • multisensor
  • analitical chemistry
  • measurement and detection of pollution
  • hydrogen cyanide
  • HCN
  • CN
  • Chemicals instrumentation

About Universitat de València

Public Agency from Spain

The University of Valencia, founded over five centuries ago by the Juries of Valencia, is a modern European public University, open to almost all branches of knowledge: social, economic and legal sciences, Basic experimental sciences, engineering and Tehcniques, health sciences, educational sciences and the humanities.
More than 41,000 undergraduate students, 4,000 postgraduate students, 2,000 students from other universities all over the world, take classes taught by more than 4,000 professors, lectures and researchers at our campuses (more than 440.000 square meters) with the support of over 1,700 administration and service staff.
Our university community is committed to being a university of reference: we are ranked 4º in Europe in receiving Erasmus students and 5ª in sending of students (Ranking Erasmus Mobility); It is fourth spanish university in research at the international level, ranking between 201 and 300, according to Shanghai Jiao Tong University Rankings.
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